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6 I 7 1 8 I I ,,,.. Fig. 23. t (expressed in the k8/k8 form) for tryptic hydrolysis of benzoyl arginin ethyl ester at +2OoC in micelles as a function of H,O/AOT, these two concentrations being expressed in moles per liter. (0)In silicone oil containing 9% (w/v) AOT, aqueous buffer concentration 200 mM; (A)in silicone oil containing 9% (w/v) AOT, aqueous buffer concentration 100 mM; (m) in silicone oil containing 3% (w/v) AOT, aqueous buffer concentration 100 mM. The upper scale indicates the percentage of water phase (v/v) for 9% (w/v) AOT in silicone oil.

D. CATALYSIS IN REVERSE MICELLES 1. Micellar Catalysis Investigations on reversed micelles as selective catalysts are now well documented. Micelles can bind a large number of substrates in their polar regions and determine specific orientations and configurations; 48 PIERRE DOUZOU interactions between the substrate and the polar headgroups. of the surfactants, between the substrate and the water, and between this water and the surfactant are quite strong and specific and result in substantial rate enhancements or retardations.

Winsor. ( a ) Liquid crystalline “middle phase (MI) indefinitely long cylinders in two-dimensional hexagonal array Ra < 1, R,= 1. (6) Liquid crystalline “neat phase” (G) indefinitely extended lamellae R, = RI = 1. (c) Liquid crystalline “inverse middle phase” (M,) indefinitely long cylinders in two-dimensional hexagonal array RI = 1; R,> 1. (d) Continuous series of isotropic solutions and continuous change of micellar configurations in equilibrium anisotropic micellar forms (M,, G,, Ma) may be present but in too low a concentration for the establishment of long-range order at the temperature and concentrations prevailing.

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